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  1. Heat pipes are passive heat transfer devices crucial for systems on spacecraft; however, they can freeze when exposed to extreme cold temperatures. The research on freezing mechanisms on wicked surfaces, such as those found in heat pipes, is limited. Surface characteristics, including surface topography, have been found to impact freezing. This work investigates freezing mechanisms on wicks during condensation freezing. Experiments were conducted in an environmental chamber at 22 °C and 60% relative humidity on three types of surfaces (i.e., plain copper, sintered heat pipe wicks, and grooved heat pipe wicks). The plain copper surface tended to freeze via ice bridging—consistent with other literature—before the grooved and sintered wicks at an average freezing time of 4.6 min with an average droplet diameter of 141.9 ± 58.1  μm at freezing. The grooved surface also froze via ice bridging but required, on average, almost double the length of time the plain copper surface took to freeze, 8.3 min with an average droplet diameter of 60.5 ± 27.9  μm at freezing. Bridges could not form between grooves, so initial freezing for each groove was stochastic. The sintered wick's surface could not propagate solely by ice bridging due to its topography, but also employed stochastic freezing and cascade freezing, which prompted more varied freezing times and an average of 10.9 min with an average droplet diameter of 97.4 ± 32.9  μm at freezing. The topography of the wicked surfaces influenced the location of droplet nucleation and, therefore, the ability for the droplet-to-droplet interaction during the freezing process. 
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  2. Semi-arid regions faced with increasingly scarce freshwater resources must manage competing demands in the food-energy-water nexus. A possible solution modifies soil hydrologic properties using biosurfactants to reduce evaporation and improve water retention. In this study, two different soil textures representative of agricultural soils in Kansas were treated with a direct application of the biosurfactant, Surfactin, and an indirect application via inoculation of Bacillus subtilis . Evaporation rates of the wetted soils were measured when exposed to artificial sunlight (1000 W/m 2 ) and compared to non-treated control soils. Experimental results indicate that both treatments alter soil moisture dynamics by increasing evaporation rates by when soil moisture is plentiful (i.e., constant rate period) and decreasing evaporation rates by when moisture is scarce (i.e., slower rate period). Furthermore, both treatments significantly reduced the soil moisture content at which the soil transitioned from constant rate to slower rate evaporation. Out of the two treatments, inoculation with B. subtilis generally produced greater changes in evaporation dynamics; for example, the treatment with B. subtilis in sandy loam soils increased constant rate periods of evaporation by 43% and decreased slower rate evaporation by 49%. In comparing the two soil textures, the sandy loam soil exhibited a larger treatment effect than the loam soil. To evaluate the potential significance of the treatment effects, a System Dynamics Model operationalized the evaporation rate results and simulated soil moisture dynamics under typical daily precipitation conditions. The results from this model indicate both treatment methods significantly altered soil moisture dynamics in the sandy loam soils and increased the probability of the soil exhibiting constant rate evaporation relative to the control soils. Overall, these findings suggest that the decrease in soil moisture threshold observed in the experimental setting could increase soil moisture availability by prolonging the constant rate stage of evaporation. As inoculation with B. subtilis in the sandy loam soil had the most pronounced effects in both the experimental and simulated contexts, future work should focus on testing this treatment in field trials with similar soil textures. 
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  3. Abstract Laser powder bed fusion (LPBF) was utilized to create a series of aluminum alloy (i.e., AlSi10Mg) 5 mm-diameter support pillars with a fixed height of 5 mm containing varying filet angles and build orientations (i.e., 0 deg, 10 deg, 20 deg, 30 deg, 40 deg, 50 deg, and 60 deg from the normal surface) to determine surface roughness and water wettability effects. From experiments, anisotropic wetting was observed due in part to the surface heterogeneity created by the LPBF process. The powder-sourced AlSi10Mg alloy, typically hydrophobic, exhibited primarily hydrophilic behavior for build angles of 0 deg and 60 deg, a mix of hydrophobic and hydrophilic behavior at build angles of 10 deg and 20 deg, and hydrophobic behavior at 30 deg, 40 deg, and 50 deg build angles. Measured surface roughness, Ra, ranged from 5 to 36 µm and varied based on location. 3D-topography maps were generated, and arithmetic mean heights, Sa, of 15.52–21.71 µm were observed; the anisotropy of roughness altered the wetting behavior, thereby prompting some hydrophilic behavior. Build angles of 30 deg and 40 deg provided for the smoothest surfaces. A significantly rougher surface was found for the 50 deg build angle. This abnormally high roughness is attributed to the melt pool contact angle having maximal capillarity with the surrounding powder bed. In this study, the critical melt pool contact angle was near equal to the build angle, suggesting that a critical build angle exists, which gives rise to pronounced melt pool wetting behavior and increased surface roughness due to enhanced wicking followed by solidification. 
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